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Our goal is to keep the book flexible to use, accessible to students, broad in scope, and authoritative, without adding bulk. However, it should always be borne in mind that much of the bulk arises from the numerous pedagogical features that we include such as Worked examples, Checklists of key equations, and the Resource section , not necessarily from density of information.
The text is still divided into three parts, but material has been moved between chapters and the chapters themselves have been reorganized. We continue to respond to the cautious shift in emphasis away from classical thermodynamics by combining several chapters in Part 1 Equilibrium , bearing in mind that some of the material will already have been covered in earlier courses. For example, material on phase diagrams no longer has its own chapter but is now distributed between Chapters 4 Physical transformation of pure substances and 5 Simple mixtures.
New Impact sections highlight the application of principles of thermodynamics to materials science, an area of growing interest to chemists. We have also paid more attention to computational chemistry, and have revised the coverage of this topic in Chapter Part 3 has lost chapters dedicated to kinetics of complex reactions and surface processes, but not the material, which we regard as highly important in a contemporary context.
We have discarded the Appendices of earlier editions. Material on mathematics covered in the appendices is now dispersed through the text in the form of Mathematical background sections, which review and expand knowledge of mathematical techniques where they are needed in the text. The review of introductory chemistry and physics, done in earlier editions in appendices, will now be found in a new Fundamentals chapter that opens the text, and particular points are developed as Brief comments or as part of Further information sections throughout the text.
By liberating these topics from their appendices and relaxing the style of presentation we believe they are more likely to be used and read. In response we have paid particular attention to making the organization flexible. The strategic aim of this revision is to make it possible to work through the text in a variety of orders and at the end of this Preface we once again include two suggested paths through the text. The concern expressed in previous editions about the level of mathematical ability has not evaporated, of course, and we have developed further our strategies for showing the absolute centrality of mathematics to physical chemistry and to make it accessible.
In addition to associating Mathematical background sections with appropriate chapters, we continue to give more help with the development of equations, motivate them, justify them, and comment on the steps.
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